      Table 1.  Crystal data and structure refinement for jsib001. 
  
  
      Identification code               jsib001 
  
      Empirical formula                 C16 H26 F6 N2 Na O3 P 
  
      Formula weight                    462.35 
  
      Temperature                       120(2) K 
  
      Wavelength                        0.71073 A 
  
      Crystal system, space group       Orthorhombic,  P2(1)2(1)2(1) 
  
      Unit cell dimensions              a = 10.010(4) A   alpha = 90 deg. 
                                        b = 12.463(5) A    beta = 90 deg. 
                                        c = 16.423(7) A   gamma = 90 deg. 
  
      Volume                            2048.8(14) A^3 
  
      Z, Calculated density             4,  1.499 Mg/m^3 
  
      Absorption coefficient            0.229 mm^-1 
  
      F(000)                            960 
  
      Crystal size                      0.20 x 0.10 x 0.08 mm 
  
      Theta range for data collection   2.05 to 28.28 deg. 
  
      Limiting indices                  -12<=h<=12, -16<=k<=16, -19<=l<=20 
  
      Reflections collected / unique    17475 / 4674 [R(int) = 0.0644] 
  
      Completeness to theta = 25.00     100.0 % 
  
      Absorption correction             Semi-empirical from equivalents 
  
      Max. and min. transmission        0.9819 and 0.7303 
  
      Refinement method                 Full-matrix least-squares on F^2 
  
      Data / restraints / parameters    4674 / 0 / 263 
  
      Goodness-of-fit on F^2            1.025 
  
      Final R indices [I>2sigma(I)]     R1 = 0.0471, wR2 = 0.0854 
  
      R indices (all data)              R1 = 0.0718, wR2 = 0.0941 
  
      Absolute structure parameter      0.36(12) 
  
      Largest diff. peak and hole       0.239 and -0.258 e.A^-3 
  
         Table 2.  Atomic coordinates ( x 10^4) and equivalent isotropic 
         displacement parameters (A^2 x 10^3) for jsib001. 
         U(eq) is defined as one third of the trace of the orthogonalized 
         Uij tensor. 
  
         ________________________________________________________________ 
  
                         x             y             z           U(eq) 
         ________________________________________________________________ 
  
          Na           9974(1)       9114(1)       8606(1)       26(1) 
          O(1)         9023(2)       9741(2)       7351(1)       35(1) 
          O(2)         9281(2)       7612(2)       7805(1)       36(1) 
          O(3)         9259(2)       7642(1)       9469(1)       31(1) 
          P(1)        13120(1)       9284(1)       8021(1)       27(1) 
          F(1)        14276(2)       8455(1)       7812(1)       40(1) 
          F(2)        13842(1)       9588(1)       8854(1)       31(1) 
          F(3)        13896(2)      10225(1)       7566(1)       40(1) 
          F(4)        11919(2)      10103(1)       8249(1)       32(1) 
          F(5)        12366(2)       8988(2)       7194(1)       42(1) 
          F(6)        12296(2)       8350(1)       8486(1)       32(1) 
          N(1)         8210(2)      10461(2)       8941(1)       29(1) 
          N(2)        10126(2)       9641(2)      10082(1)       22(1) 
          C(1)         9528(2)      10690(2)      10200(2)       24(1) 
          C(2)         9876(3)      11305(2)      10872(2)       30(1) 
          C(3)         9425(3)      12347(2)      10965(2)       37(1) 
          C(4)         8617(3)      12783(3)      10377(2)       45(1) 
          C(5)         8218(3)      12177(2)       9716(2)       41(1) 
          C(6)         8651(3)      11111(2)       9616(2)       28(1) 
          C(7)         6996(3)       9864(3)       9173(2)       42(1) 
          C(8)         7978(3)      11069(2)       8186(2)       38(1) 
          C(9)         7824(3)      10347(3)       7448(2)       43(1) 
          C(10)        8952(4)       8885(3)       6763(2)       44(1) 
          C(11)        8434(3)       7862(3)       7138(2)       46(1) 
          C(12)        8818(3)       6708(2)       8270(2)       37(1) 
          C(13)        9561(3)       6675(2)       9045(2)       34(1) 
          C(14)        9830(3)       7697(2)      10262(2)       35(1) 
          C(15)        9539(3)       8797(2)      10596(2)       29(1) 
          C(16)       11579(2)       9685(2)      10223(2)       31(1) 
         ________________________________________________________________ 
  
           Table 3.  Bond lengths [A] and angles [deg] for jsib001. 
           _____________________________________________________________ 
  
            Na-F(4)                       2.377(2) 
            Na-O(2)                       2.391(2) 
            Na-O(1)                       2.400(2) 
            Na-O(3)                       2.427(2) 
            Na-N(1)                       2.498(3) 
            Na-N(2)                       2.517(2) 
            Na-F(6)                       2.520(2) 
            Na-P(1)                       3.2994(17) 
            O(1)-C(9)                     1.426(3) 
            O(1)-C(10)                    1.440(4) 
            O(2)-C(11)                    1.420(4) 
            O(2)-C(12)                    1.438(3) 
            O(3)-C(14)                    1.424(3) 
            O(3)-C(13)                    1.424(3) 
            P(1)-F(1)                     1.5885(18) 
            P(1)-F(3)                     1.5926(17) 
            P(1)-F(2)                     1.5940(17) 
            P(1)-F(5)                     1.5966(18) 
            P(1)-F(6)                     1.6186(17) 
            P(1)-F(4)                     1.6219(17) 
            N(1)-C(6)                     1.441(3) 
            N(1)-C(8)                     1.472(3) 
            N(1)-C(7)                     1.476(3) 
            N(2)-C(1)                     1.452(3) 
            N(2)-C(15)                    1.471(3) 
            N(2)-C(16)                    1.474(3) 
            C(1)-C(2)                     1.388(4) 
            C(1)-C(6)                     1.402(4) 
            C(2)-C(3)                     1.384(4) 
            C(2)-H(2A)                    0.9500 
            C(3)-C(4)                     1.373(4) 
            C(3)-H(3A)                    0.9500 
            C(4)-C(5)                     1.380(4) 
            C(4)-H(4A)                    0.9500 
            C(5)-C(6)                     1.408(4) 
            C(5)-H(5A)                    0.9500 
            C(7)-H(7A)                    0.9800 
            C(7)-H(7B)                    0.9800 
            C(7)-H(7C)                    0.9800 
            C(8)-C(9)                     1.517(4) 
            C(8)-H(8A)                    0.9900 
            C(8)-H(8B)                    0.9900 
            C(9)-H(9A)                    0.9900 
            C(9)-H(9B)                    0.9900 
            C(10)-C(11)                   1.508(5) 
            C(10)-H(10A)                  0.9900 
            C(10)-H(10B)                  0.9900 
            C(11)-H(11A)                  0.9900 
            C(11)-H(11B)                  0.9900 
            C(12)-C(13)                   1.474(4) 
            C(12)-H(12A)                  0.9900 
            C(12)-H(12B)                  0.9900 
            C(13)-H(13A)                  0.9900 
            C(13)-H(13B)                  0.9900 
            C(14)-C(15)                   1.505(4) 
            C(14)-H(14A)                  0.9900 
            C(14)-H(14B)                  0.9900 
            C(15)-H(15A)                  0.9900 
            C(15)-H(15B)                  0.9900 
            C(16)-H(16A)                  0.9800 
            C(16)-H(16B)                  0.9800 
            C(16)-H(16C)                  0.9800 
  
            F(4)-Na-O(2)                120.53(8) 
            F(4)-Na-O(1)                 86.83(7) 
            O(2)-Na-O(1)                 70.58(8) 
            F(4)-Na-O(3)                141.03(7) 
            O(2)-Na-O(3)                 69.14(8) 
            O(1)-Na-O(3)                129.09(8) 
            F(4)-Na-N(1)                106.55(8) 
            O(2)-Na-N(1)                116.26(8) 
            O(1)-Na-N(1)                 71.95(8) 
            O(3)-Na-N(1)                 99.82(8) 
            F(4)-Na-N(2)                 93.03(7) 
            O(2)-Na-N(2)                138.74(8) 
            O(1)-Na-N(2)                140.00(9) 
            O(3)-Na-N(2)                 69.63(7) 
            N(1)-Na-N(2)                 69.81(7) 
            F(4)-Na-F(6)                 54.66(6) 
            O(2)-Na-F(6)                 85.91(7) 
            O(1)-Na-F(6)                114.97(7) 
            O(3)-Na-F(6)                 91.82(7) 
            N(1)-Na-F(6)                157.43(8) 
            N(2)-Na-F(6)                 96.77(7) 
            F(4)-Na-P(1)                 27.56(4) 
            O(2)-Na-P(1)                 99.61(6) 
            O(1)-Na-P(1)                 96.20(6) 
            O(3)-Na-P(1)                120.00(6) 
            N(1)-Na-P(1)                134.11(7) 
            N(2)-Na-P(1)                101.90(6) 
            F(6)-Na-P(1)                 28.48(4) 
            C(9)-O(1)-C(10)             115.2(2) 
            C(9)-O(1)-Na                114.19(16) 
            C(10)-O(1)-Na               110.72(17) 
            C(11)-O(2)-C(12)            112.9(2) 
            C(11)-O(2)-Na               115.23(18) 
            C(12)-O(2)-Na               114.50(16) 
            C(14)-O(3)-C(13)            113.7(2) 
            C(14)-O(3)-Na               112.32(16) 
            C(13)-O(3)-Na               106.94(16) 
            F(1)-P(1)-F(3)               91.29(10) 
            F(1)-P(1)-F(2)               90.57(9) 
            F(3)-P(1)-F(2)               90.38(9) 
            F(1)-P(1)-F(5)               90.63(10) 
            F(3)-P(1)-F(5)               90.11(10) 
            F(2)-P(1)-F(5)              178.69(10) 
            F(1)-P(1)-F(6)               90.31(10) 
            F(3)-P(1)-F(6)              178.38(10) 
            F(2)-P(1)-F(6)               89.79(9) 
            F(5)-P(1)-F(6)               89.69(10) 
            F(1)-P(1)-F(4)              178.34(10) 
            F(3)-P(1)-F(4)               90.36(10) 
            F(2)-P(1)-F(4)               89.29(9) 
            F(5)-P(1)-F(4)               89.49(9) 
            F(6)-P(1)-F(4)               88.03(9) 
            F(1)-P(1)-Na                135.77(8) 
            F(3)-P(1)-Na                130.47(7) 
            F(2)-P(1)-Na                101.39(7) 
            F(5)-P(1)-Na                 77.38(7) 
            F(6)-P(1)-Na                 47.94(6) 
            F(4)-P(1)-Na                 42.69(6) 
            P(1)-F(4)-Na                109.75(9) 
            P(1)-F(6)-Na                103.58(8) 
            C(6)-N(1)-C(8)              114.0(2) 
            C(6)-N(1)-C(7)              109.7(2) 
            C(8)-N(1)-C(7)              110.4(2) 
            C(6)-N(1)-Na                109.31(15) 
            C(8)-N(1)-Na                105.74(17) 
            C(7)-N(1)-Na                107.47(17) 
            C(1)-N(2)-C(15)             113.8(2) 
            C(1)-N(2)-C(16)             110.7(2) 
            C(15)-N(2)-C(16)            109.3(2) 
            C(1)-N(2)-Na                109.79(16) 
            C(15)-N(2)-Na               110.01(16) 
            C(16)-N(2)-Na               102.73(16) 
            C(2)-C(1)-C(6)              119.7(3) 
            C(2)-C(1)-N(2)              120.0(2) 
            C(6)-C(1)-N(2)              120.3(2) 
            C(3)-C(2)-C(1)              121.6(3) 
            C(3)-C(2)-H(2A)             119.2 
            C(1)-C(2)-H(2A)             119.2 
            C(4)-C(3)-C(2)              119.1(3) 
            C(4)-C(3)-H(3A)             120.5 
            C(2)-C(3)-H(3A)             120.5 
            C(3)-C(4)-C(5)              120.5(3) 
            C(3)-C(4)-H(4A)             119.8 
            C(5)-C(4)-H(4A)             119.8 
            C(4)-C(5)-C(6)              121.3(3) 
            C(4)-C(5)-H(5A)             119.4 
            C(6)-C(5)-H(5A)             119.4 
            C(1)-C(6)-C(5)              117.7(3) 
            C(1)-C(6)-N(1)              120.5(2) 
            C(5)-C(6)-N(1)              121.8(3) 
            N(1)-C(7)-H(7A)             109.5 
            N(1)-C(7)-H(7B)             109.5 
            H(7A)-C(7)-H(7B)            109.5 
            N(1)-C(7)-H(7C)             109.5 
            H(7A)-C(7)-H(7C)            109.5 
            H(7B)-C(7)-H(7C)            109.5 
            N(1)-C(8)-C(9)              112.5(2) 
            N(1)-C(8)-H(8A)             109.1 
            C(9)-C(8)-H(8A)             109.1 
            N(1)-C(8)-H(8B)             109.1 
            C(9)-C(8)-H(8B)             109.1 
            H(8A)-C(8)-H(8B)            107.8 
            O(1)-C(9)-C(8)              108.6(2) 
            O(1)-C(9)-H(9A)             110.0 
            C(8)-C(9)-H(9A)             110.0 
            O(1)-C(9)-H(9B)             110.0 
            C(8)-C(9)-H(9B)             110.0 
            H(9A)-C(9)-H(9B)            108.4 
            O(1)-C(10)-C(11)            111.7(3) 
            O(1)-C(10)-H(10A)           109.3 
            C(11)-C(10)-H(10A)          109.3 
            O(1)-C(10)-H(10B)           109.3 
            C(11)-C(10)-H(10B)          109.3 
            H(10A)-C(10)-H(10B)         107.9 
            O(2)-C(11)-C(10)            107.1(3) 
            O(2)-C(11)-H(11A)           110.3 
            C(10)-C(11)-H(11A)          110.3 
            O(2)-C(11)-H(11B)           110.3 
            C(10)-C(11)-H(11B)          110.3 
            H(11A)-C(11)-H(11B)         108.5 
            O(2)-C(12)-C(13)            108.5(2) 
            O(2)-C(12)-H(12A)           110.0 
            C(13)-C(12)-H(12A)          110.0 
            O(2)-C(12)-H(12B)           110.0 
            C(13)-C(12)-H(12B)          110.0 
            H(12A)-C(12)-H(12B)         108.4 
            O(3)-C(13)-C(12)            107.0(2) 
            O(3)-C(13)-H(13A)           110.3 
            C(12)-C(13)-H(13A)          110.3 
            O(3)-C(13)-H(13B)           110.3 
            C(12)-C(13)-H(13B)          110.3 
            H(13A)-C(13)-H(13B)         108.6 
            O(3)-C(14)-C(15)            107.4(2) 
            O(3)-C(14)-H(14A)           110.2 
            C(15)-C(14)-H(14A)          110.2 
            O(3)-C(14)-H(14B)           110.2 
            C(15)-C(14)-H(14B)          110.2 
            H(14A)-C(14)-H(14B)         108.5 
            N(2)-C(15)-C(14)            111.4(2) 
            N(2)-C(15)-H(15A)           109.4 
            C(14)-C(15)-H(15A)          109.4 
            N(2)-C(15)-H(15B)           109.4 
            C(14)-C(15)-H(15B)          109.4 
            H(15A)-C(15)-H(15B)         108.0 
            N(2)-C(16)-H(16A)           109.5 
            N(2)-C(16)-H(16B)           109.5 
            H(16A)-C(16)-H(16B)         109.5 
            N(2)-C(16)-H(16C)           109.5 
            H(16A)-C(16)-H(16C)         109.5 
            H(16B)-C(16)-H(16C)         109.5 
           _____________________________________________________________ 
  
           Symmetry transformations used to generate equivalent atoms: 
            
  
    Table 4.  Anisotropic displacement parameters (A^2 x 10^3) for jsib001. 
    The anisotropic displacement factor exponent takes the form: 
    -2 pi^2 [ h^2 a*^2 U11 + ... + 2 h k a* b* U12 ] 
  
    _______________________________________________________________________ 
  
              U11        U22        U33        U23        U13        U12 
    _______________________________________________________________________ 
  
    Na       24(1)      29(1)      25(1)       0(1)      -1(1)      -3(1) 
    O(1)     33(1)      45(1)      28(1)       1(1)      -9(1)      -4(1) 
    O(2)     39(1)      40(1)      28(1)      -4(1)      -8(1)      -7(1) 
    O(3)     37(1)      22(1)      34(1)      -4(1)       1(1)      -1(1) 
    P(1)     24(1)      32(1)      25(1)       7(1)       1(1)       0(1) 
    F(1)     41(1)      42(1)      38(1)       3(1)       7(1)      13(1) 
    F(2)     27(1)      35(1)      32(1)       5(1)      -6(1)      -2(1) 
    F(3)     37(1)      41(1)      43(1)      18(1)      12(1)      -3(1) 
    F(4)     27(1)      34(1)      35(1)       9(1)       2(1)       4(1) 
    F(5)     44(1)      57(1)      26(1)       3(1)      -7(1)      -3(1) 
    F(6)     34(1)      26(1)      35(1)       7(1)       1(1)      -6(1) 
    N(1)     23(1)      34(1)      28(1)       3(1)      -7(1)       0(1) 
    N(2)     22(1)      21(1)      22(1)       3(1)       1(1)       1(1) 
    C(1)     20(1)      27(2)      24(2)       1(1)       4(1)      -1(1) 
    C(2)     26(2)      32(2)      33(2)      -4(1)       0(1)       0(1) 
    C(3)     29(2)      37(2)      44(2)     -12(2)       5(1)      -1(1) 
    C(4)     44(2)      27(2)      63(3)      -8(2)       1(2)      10(2) 
    C(5)     38(2)      33(2)      52(2)       3(2)      -9(2)      14(2) 
    C(6)     22(1)      28(2)      33(2)       1(1)      -1(1)       0(1) 
    C(7)     31(2)      56(2)      37(2)      -2(2)      -1(2)     -12(2) 
    C(8)     33(2)      41(2)      39(2)       9(2)      -6(1)       7(1) 
    C(9)     34(2)      62(2)      32(2)      12(2)     -14(1)       5(2) 
    C(10)    52(2)      55(2)      26(2)      -2(2)      -8(2)      -9(2) 
    C(11)    49(2)      52(2)      37(2)     -11(2)     -13(2)      -9(2) 
    C(12)    42(2)      26(2)      44(2)      -5(2)      -1(2)     -12(1) 
    C(13)    35(2)      24(2)      42(2)      -7(2)       8(2)      -6(1) 
    C(14)    52(2)      23(2)      29(2)       6(1)       4(2)      -7(2) 
    C(15)    35(2)      29(2)      24(2)       3(1)       7(1)      -3(1) 
    C(16)    25(1)      37(2)      31(2)      -3(1)      -1(1)       8(1) 
    _______________________________________________________________________ 
  
         Table 5.  Hydrogen coordinates ( x 10^4) and isotropic 
         displacement parameters (A^2 x 10^3) for jsib001. 
  
         ________________________________________________________________ 
  
                         x             y             z           U(eq) 
         ________________________________________________________________ 
  
          H(2A)       10439         11003         11277          36 
          H(3A)        9671         12755         11430          44 
          H(4A)        8330         13507         10424          54 
          H(5A)        7639         12486          9322          49 
          H(7A)        6285         10372          9313          63 
          H(7B)        7190          9408          9645          63 
          H(7C)        6707          9415          8716          63 
          H(8A)        8737         11564          8094          45 
          H(8B)        7160         11508          8248          45 
          H(9A)        7056          9857          7526          51 
          H(9B)        7658         10785          6956          51 
          H(10A)       9853          8756          6535          53 
          H(10B)       8357          9103          6311          53 
          H(11A)       7503          7960          7327          55 
          H(11B)       8450          7274          6732          55 
          H(12A)       8969          6036          7962          45 
          H(12B)       7849          6777          8378          45 
          H(13A)       9284          6045          9371          41 
          H(13B)      10533          6625          8940          41 
          H(14A)      10807          7577         10233          41 
          H(14B)       9435          7140         10618          41 
          H(15A)       8560          8902         10628          35 
          H(15B)       9906          8854         11154          35 
          H(16A)      11753          9885         10790          47 
          H(16B)      11980         10219          9859          47 
          H(16C)      11971          8979         10113          47 
         ________________________________________________________________ 
  
         Table 6.  Torsion angles [deg] for jsib001. 
         ________________________________________________________________ 
  
          F(4)-Na-O(1)-C(9)                                  -120.68(19) 
          O(2)-Na-O(1)-C(9)                                   115.33(19) 
          O(3)-Na-O(1)-C(9)                                    75.9(2) 
          N(1)-Na-O(1)-C(9)                                   -12.13(18) 
          N(2)-Na-O(1)-C(9)                                   -29.7(2) 
          F(6)-Na-O(1)-C(9)                                  -169.00(18) 
          P(1)-Na-O(1)-C(9)                                  -146.63(18) 
          F(4)-Na-O(1)-C(10)                                  107.32(19) 
          O(2)-Na-O(1)-C(10)                                  -16.67(18) 
          O(3)-Na-O(1)-C(10)                                  -56.1(2) 
          N(1)-Na-O(1)-C(10)                                 -144.1(2) 
          N(2)-Na-O(1)-C(10)                                 -161.75(18) 
          F(6)-Na-O(1)-C(10)                                   59.0(2) 
          P(1)-Na-O(1)-C(10)                                   81.37(18) 
          F(4)-Na-O(2)-C(11)                                  -87.7(2) 
          O(1)-Na-O(2)-C(11)                                  -13.71(19) 
          O(3)-Na-O(2)-C(11)                                  134.5(2) 
          N(1)-Na-O(2)-C(11)                                   43.6(2) 
          N(2)-Na-O(2)-C(11)                                  132.4(2) 
          F(6)-Na-O(2)-C(11)                                 -132.0(2) 
          P(1)-Na-O(2)-C(11)                                 -106.94(19) 
          F(4)-Na-O(2)-C(12)                                  138.83(18) 
          O(1)-Na-O(2)-C(12)                                 -147.2(2) 
          O(3)-Na-O(2)-C(12)                                    1.00(18) 
          N(1)-Na-O(2)-C(12)                                  -89.9(2) 
          N(2)-Na-O(2)-C(12)                                   -1.1(2) 
          F(6)-Na-O(2)-C(12)                                   94.51(19) 
          P(1)-Na-O(2)-C(12)                                  119.57(18) 
          F(4)-Na-O(3)-C(14)                                   43.3(2) 
          O(2)-Na-O(3)-C(14)                                  156.43(19) 
          O(1)-Na-O(3)-C(14)                                 -163.75(17) 
          N(1)-Na-O(3)-C(14)                                  -89.08(18) 
          N(2)-Na-O(3)-C(14)                                  -25.05(17) 
          F(6)-Na-O(3)-C(14)                                   71.50(18) 
          P(1)-Na-O(3)-C(14)                                   67.22(18) 
          F(4)-Na-O(3)-C(13)                                  -82.2(2) 
          O(2)-Na-O(3)-C(13)                                   31.01(17) 
          O(1)-Na-O(3)-C(13)                                   70.8(2) 
          N(1)-Na-O(3)-C(13)                                  145.50(17) 
          N(2)-Na-O(3)-C(13)                                 -150.47(18) 
          F(6)-Na-O(3)-C(13)                                  -53.92(17) 
          P(1)-Na-O(3)-C(13)                                  -58.20(18) 
          F(4)-Na-P(1)-F(1)                                   179.09(14) 
          O(2)-Na-P(1)-F(1)                                   -38.80(12) 
          O(1)-Na-P(1)-F(1)                                  -110.09(11) 
          O(3)-Na-P(1)-F(1)                                    32.58(13) 
          N(1)-Na-P(1)-F(1)                                   179.10(12) 
          N(2)-Na-P(1)-F(1)                                   105.77(12) 
          F(6)-Na-P(1)-F(1)                                    23.57(12) 
          F(4)-Na-P(1)-F(3)                                   -24.12(12) 
          O(2)-Na-P(1)-F(3)                                   117.98(11) 
          O(1)-Na-P(1)-F(3)                                    46.69(11) 
          O(3)-Na-P(1)-F(3)                                  -170.64(11) 
          N(1)-Na-P(1)-F(3)                                   -24.11(14) 
          N(2)-Na-P(1)-F(3)                                   -97.44(11) 
          F(6)-Na-P(1)-F(3)                                  -179.64(13) 
          F(4)-Na-P(1)-F(2)                                    76.29(10) 
          O(2)-Na-P(1)-F(2)                                  -141.60(9) 
          O(1)-Na-P(1)-F(2)                                   147.11(9) 
          O(3)-Na-P(1)-F(2)                                   -70.22(9) 
          N(1)-Na-P(1)-F(2)                                    76.30(11) 
          N(2)-Na-P(1)-F(2)                                     2.97(9) 
          F(6)-Na-P(1)-F(2)                                   -79.23(11) 
          F(4)-Na-P(1)-F(5)                                  -103.26(11) 
          O(2)-Na-P(1)-F(5)                                    38.85(9) 
          O(1)-Na-P(1)-F(5)                                   -32.44(9) 
          O(3)-Na-P(1)-F(5)                                   110.23(10) 
          N(1)-Na-P(1)-F(5)                                  -103.25(11) 
          N(2)-Na-P(1)-F(5)                                  -176.58(9) 
          F(6)-Na-P(1)-F(5)                                   101.22(11) 
          F(4)-Na-P(1)-F(6)                                   155.52(12) 
          O(2)-Na-P(1)-F(6)                                   -62.37(10) 
          O(1)-Na-P(1)-F(6)                                  -133.66(10) 
          O(3)-Na-P(1)-F(6)                                     9.01(10) 
          N(1)-Na-P(1)-F(6)                                   155.53(12) 
          N(2)-Na-P(1)-F(6)                                    82.20(10) 
          O(2)-Na-P(1)-F(4)                                   142.11(11) 
          O(1)-Na-P(1)-F(4)                                    70.82(10) 
          O(3)-Na-P(1)-F(4)                                  -146.51(10) 
          N(1)-Na-P(1)-F(4)                                     0.01(12) 
          N(2)-Na-P(1)-F(4)                                   -73.32(10) 
          F(6)-Na-P(1)-F(4)                                  -155.52(12) 
          F(1)-P(1)-F(4)-Na                                   -23(4) 
          F(3)-P(1)-F(4)-Na                                   161.89(9) 
          F(2)-P(1)-F(4)-Na                                  -107.74(9) 
          F(5)-P(1)-F(4)-Na                                    71.78(9) 
          F(6)-P(1)-F(4)-Na                                   -17.93(9) 
          O(2)-Na-F(4)-P(1)                                   -44.67(12) 
          O(1)-Na-F(4)-P(1)                                  -109.88(9) 
          O(3)-Na-F(4)-P(1)                                    49.44(14) 
          N(1)-Na-F(4)-P(1)                                  -179.99(9) 
          N(2)-Na-F(4)-P(1)                                   110.18(9) 
          F(6)-Na-F(4)-P(1)                                    14.02(7) 
          F(1)-P(1)-F(6)-Na                                  -163.81(9) 
          F(3)-P(1)-F(6)-Na                                    10(4) 
          F(2)-P(1)-F(6)-Na                                   105.62(9) 
          F(5)-P(1)-F(6)-Na                                   -73.18(9) 
          F(4)-P(1)-F(6)-Na                                    16.33(8) 
          F(4)-Na-F(6)-P(1)                                   -13.59(7) 
          O(2)-Na-F(6)-P(1)                                   118.87(9) 
          O(1)-Na-F(6)-P(1)                                    52.50(11) 
          O(3)-Na-F(6)-P(1)                                  -172.20(9) 
          N(1)-Na-F(6)-P(1)                                   -50.8(2) 
          N(2)-Na-F(6)-P(1)                                  -102.50(9) 
          F(4)-Na-N(1)-C(6)                                   -60.41(17) 
          O(2)-Na-N(1)-C(6)                                   162.07(16) 
          O(1)-Na-N(1)-C(6)                                  -141.34(18) 
          O(3)-Na-N(1)-C(6)                                    90.59(17) 
          N(2)-Na-N(1)-C(6)                                    26.70(16) 
          F(6)-Na-N(1)-C(6)                                   -29.4(3) 
          P(1)-Na-N(1)-C(6)                                   -60.41(19) 
          F(4)-Na-N(1)-C(8)                                    62.73(18) 
          O(2)-Na-N(1)-C(8)                                   -74.79(18) 
          O(1)-Na-N(1)-C(8)                                   -18.20(16) 
          O(3)-Na-N(1)-C(8)                                  -146.27(17) 
          N(2)-Na-N(1)-C(8)                                   149.84(19) 
          F(6)-Na-N(1)-C(8)                                    93.7(2) 
          P(1)-Na-N(1)-C(8)                                    62.73(19) 
          F(4)-Na-N(1)-C(7)                                  -179.39(16) 
          O(2)-Na-N(1)-C(7)                                    43.08(19) 
          O(1)-Na-N(1)-C(7)                                    99.67(18) 
          O(3)-Na-N(1)-C(7)                                   -28.40(18) 
          N(2)-Na-N(1)-C(7)                                   -92.29(18) 
          F(6)-Na-N(1)-C(7)                                  -148.4(2) 
          P(1)-Na-N(1)-C(7)                                  -179.40(14) 
          F(4)-Na-N(2)-C(1)                                    83.02(16) 
          O(2)-Na-N(2)-C(1)                                  -130.70(17) 
          O(1)-Na-N(2)-C(1)                                    -5.6(2) 
          O(3)-Na-N(2)-C(1)                                  -132.80(17) 
          N(1)-Na-N(2)-C(1)                                   -23.50(15) 
          F(6)-Na-N(2)-C(1)                                   137.78(15) 
          P(1)-Na-N(2)-C(1)                                   109.37(15) 
          F(4)-Na-N(2)-C(15)                                 -151.05(16) 
          O(2)-Na-N(2)-C(15)                                   -4.8(2) 
          O(1)-Na-N(2)-C(15)                                  120.28(18) 
          O(3)-Na-N(2)-C(15)                                   -6.87(16) 
          N(1)-Na-N(2)-C(15)                                  102.42(18) 
          F(6)-Na-N(2)-C(15)                                  -96.30(17) 
          P(1)-Na-N(2)-C(15)                                 -124.71(16) 
          F(4)-Na-N(2)-C(16)                                  -34.75(17) 
          O(2)-Na-N(2)-C(16)                                  111.53(19) 
          O(1)-Na-N(2)-C(16)                                 -123.42(18) 
          O(3)-Na-N(2)-C(16)                                  109.43(18) 
          N(1)-Na-N(2)-C(16)                                 -141.27(18) 
          F(6)-Na-N(2)-C(16)                                   20.01(17) 
          P(1)-Na-N(2)-C(16)                                   -8.40(17) 
          C(15)-N(2)-C(1)-C(2)                                 78.2(3) 
          C(16)-N(2)-C(1)-C(2)                                -45.3(3) 
          Na-N(2)-C(1)-C(2)                                  -158.1(2) 
          C(15)-N(2)-C(1)-C(6)                               -105.2(3) 
          C(16)-N(2)-C(1)-C(6)                                131.3(3) 
          Na-N(2)-C(1)-C(6)                                    18.6(3) 
          C(6)-C(1)-C(2)-C(3)                                  -2.8(4) 
          N(2)-C(1)-C(2)-C(3)                                 173.8(3) 
          C(1)-C(2)-C(3)-C(4)                                  -0.2(4) 
          C(2)-C(3)-C(4)-C(5)                                   2.5(5) 
          C(3)-C(4)-C(5)-C(6)                                  -1.7(5) 
          C(2)-C(1)-C(6)-C(5)                                   3.5(4) 
          N(2)-C(1)-C(6)-C(5)                                -173.1(3) 
          C(2)-C(1)-C(6)-N(1)                                -176.0(2) 
          N(2)-C(1)-C(6)-N(1)                                   7.3(4) 
          C(4)-C(5)-C(6)-C(1)                                  -1.4(5) 
          C(4)-C(5)-C(6)-N(1)                                 178.2(3) 
          C(8)-N(1)-C(6)-C(1)                                -147.2(3) 
          C(7)-N(1)-C(6)-C(1)                                  88.5(3) 
          Na-N(1)-C(6)-C(1)                                   -29.1(3) 
          C(8)-N(1)-C(6)-C(5)                                  33.3(4) 
          C(7)-N(1)-C(6)-C(5)                                 -91.0(3) 
          Na-N(1)-C(6)-C(5)                                   151.4(2) 
          C(6)-N(1)-C(8)-C(9)                                 167.0(2) 
          C(7)-N(1)-C(8)-C(9)                                 -69.0(3) 
          Na-N(1)-C(8)-C(9)                                    46.9(3) 
          C(10)-O(1)-C(9)-C(8)                                169.8(2) 
          Na-O(1)-C(9)-C(8)                                    40.0(3) 
          N(1)-C(8)-C(9)-O(1)                                 -60.4(3) 
          C(9)-O(1)-C(10)-C(11)                               -86.9(3) 
          Na-O(1)-C(10)-C(11)                                  44.5(3) 
          C(12)-O(2)-C(11)-C(10)                              174.1(2) 
          Na-O(2)-C(11)-C(10)                                  39.9(3) 
          O(1)-C(10)-C(11)-O(2)                               -56.3(3) 
          C(11)-O(2)-C(12)-C(13)                             -166.6(3) 
          Na-O(2)-C(12)-C(13)                                 -32.0(3) 
          C(14)-O(3)-C(13)-C(12)                              175.7(2) 
          Na-O(3)-C(13)-C(12)                                 -59.7(2) 
          O(2)-C(12)-C(13)-O(3)                                61.9(3) 
          C(13)-O(3)-C(14)-C(15)                              174.6(2) 
          Na-O(3)-C(14)-C(15)                                  53.0(3) 
          C(1)-N(2)-C(15)-C(14)                               160.3(2) 
          C(16)-N(2)-C(15)-C(14)                              -75.4(3) 
          Na-N(2)-C(15)-C(14)                                  36.7(3) 
          O(3)-C(14)-C(15)-N(2)                               -60.4(3) 
         ________________________________________________________________ 
  
         Symmetry transformations used to generate equivalent atoms: 
          
  
